منابع مشابه
Equilibrium Potentials of Membrane Electrodes ( glass electrode / pH ) JUI
A simple thermodynamic theory of the equilibrium potentials of membrane electrodes is formulated and applied to the glass electrode for measurement of pH. The new formulation assumes the selective adsorption or binding of specific ions on the surface of the membrane which may or may not be permeable to the ion, and includes the conventional derivation based on reversible ion transport across me...
متن کاملDevelopment of the Glass Electrode and the pH Response
The glass electrode is the most commonly used device to access the pH of an aqueous solution. It attains highly accurate measurements via simple and well-established procedures. However, the reasons why the glass electrode potential scales with hydrogen ion concentration according to almost Nernstian potential values have been long-standing challenges to explain. Only in the past 50 years has a...
متن کاملA GLASS ELECTRODE APPARATUS FOR MEASURING THE pH VALUES OF VERY SMALL VOLUMES OF SOLUTION
A glass electrode apparatus is described with which pH measurements can be made with as small volumes as 2 drops (about 0.14 cc.) of solution. Using this apparatus the change of pH of the vacuolar sap of Nitella, due to the penetration of brilliant cresyl blue, has been readily followed. The sap and the dye have been found to poison the usual type of hydrogen electrode.
متن کاملAnalysis of Acid Papers by Non-Aqueous Solvent Extraction- Spectrophotometry and Upside-down pH Glass Electrode
Non-aqueous solvent extraction of acid in papers is described; the process employs a liquid ion-exchanger in chloroform. The amounts of the acid in the so-called acid paper are determined by the normal method of aqueous extraction and by the organic solvent extraction and the values are compared. The results of investigation confirm that the acid content of the acid paper must be determined by ...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 1991
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.7.supple_1667